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Academic Year/course: 2017/18

30102 - Chemistry


Syllabus Information

Academic Year:
2017/18
Subject:
30102 - Chemistry
Faculty / School:
175 - Escuela Universitaria Politécnica de La Almunia
179 - Centro Universitario de la Defensa - Zaragoza
Degree:
425 - Bachelor's Degree in Industrial Organisational Engineering
457 - Bachelor's Degree in Industrial Organisational Engineering
563 - Bachelor's Degree in Industrial Organisational Engineering
ECTS:
6.0
Year:
1
Semester:
425 - First semester
563 - Second semester
457 - Second semester
Subject Type:
Basic Education
Module:
---

5.1. Methodological overview

 

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 The organization of teaching will be carried out using the following steps:

- Theory Classes: Theoretical activities carried out mainly through exposition by the teacher, where the theoretical supports of the subject are displayed, highlighting the fundamental, structuring them in topics and or sections, interrelating them.

- Practical Classes: The teacher resolves practical problems or cases for demonstrative purposes. This type of teaching complements the theory shown in the lectures with practical aspects.

- Laboratory Workshop: The lecture group is divided up into various groups, according to the number of registered students, but never with more than 16 students, in order to make up smaller sized groups.

- Individual Tutorials: Those carried out giving individual, personalized attention with a teacher from the department. Said tutorials may be in person or online.

 

DEFENCE

 

In order to get the objectives described in the previous sections the following learning activities will be carried out: lectures, practical and problem solving sessions, laboratory sessions.

5.2. Learning tasks

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The subject has 6 ECTS credits, which represents 150 hours of student work in the subject during the trimester, in other words, 10 hours per week for 15 weeks of class.

A summary of a weekly timetable guide can be seen in the following table. These figures are obtained from the subject file in the Accreditation Report of the degree, taking into account the level of experimentation considered for the said subject is moderate.

Activity

Weekly  school hours

Lectures

2

Laboratory Workshop

2

Other Activities

6

 

 

 

DEFENCE

  1. lectures,
  2. practical and problem solving sessions,
  3. laboratory sessions.

 

5.3. Syllabus

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THEORETICAL CONTENTS

 

 

 

Module

Contents

 

1.    THE ATOM AND THE PERIODIC SYSTEM

 

 

 

Topic 1.-  The atom.

Elemental particles. Atomic models. The Bohr atom. The quantum mechanical model. Atomic orbitals; quantum numbers. Principles for the electronic construction of atoms.

 

Topic 2.- General overview of the periodic table

 Description of the current periodic table: groups and periods. Study of the electron shell and the periodic system. Periodic properties.

 

 

2.  THE CHEMICAL BOND

 

Topic 3.- The ionic bond

General characteristics of the ionic bond. Network energy. General properties of ionic compounds.

 

Topic 4.- The covalent bond

Simplified model: the Lewis theory. Bond polarity and geometry. Valence bond theory. Orbital hybridization. Molecular orbital theory.

 

Topic 5.- The metallic bond

General characteristics of metals. Theories of the metallic bond: the electron sea theory and valence bond theory. Alloys: classes.

 

3.    BONDS BETWEEN MOLECULES

 

Topic 6.- Intermolecular bonds

Van der Waal forces. Hydrogen bonds.

 

 

4.   AGGREGATION STATES

 

Topic 7.- The gas state

General characteristics of gases. Laws that govern the gas state. Equations of state. Kinetic theory. Gas mixtures: Dalton's Law. Gas diffusion and effusion: Graham's Law. Real gases: The Van der Waal equation.

 

Topic 8.- The liquid state

General characteristics of liquids. Vapour pressure. The effect of temperature on vapour pressure. Critical phenomena. Condensation of vapours and gases. Solidification.

 

Topic 9.- The solid state

Characteristics of solids. Classes of crystal network. Classes of solids based on bonding type. The phase rule and the triple point.

 

 

5.   INTRODUCTION TO THE STUDY OF SOLUTIONS

 

Topic 10.- Introduction to the study of solutions

Disperse systems. Types of solutions. Means of expressing concentration. Solid-in-liquid solutions. Liquid-in-liquid solutions. Gas-in-liquid solutions. Colligative properties of solutions. Colloidal solutions.

 

 

6.  INTRODUCTION TO THE STUDY OF REACTIONS

 

Topic 11.- Chemical equilibrium

The concept of reaction rate. Reversible and irreversible reactions. Chemical equilibrium: the equilibrium constant. Le Chatelier's principle. Stable, unstable and metastable systems.

 

Topic 12.- Neutralisation reactions

The acid-base concept. Aqueous solutions: pH of aqueous solutions. Acid-base strengths. Equilibrium constants. Salt hydrolysis.

 

7.    ORGANIC CHEMISTRY

 

Topic 13.- Organic chemistry

The properties of carbon. Types of organic substances Isomers. Organic chemical reactions. Polymers

 

 

 

 

 

PRACTICAL CONTENTS

 

 

Practical 1

 

Standards in Chemical Laboratory

Techniques, Equipment and Safety

 

Practical 2

 

Solution Preparation

Na2CO3 0,1 M from Na2CO3 solid; CaCl2 0,1 M from CaCl2 2 M

 

Practical 3

 

Filtration

Gravity Filtration and Vacuum Filtration

 

Practical 4

 

Volumetric Analysis

Water hardness; carbonates and bicarbonates in water.

 

Practical 5

 

Distillation

 

 

 

DEFENCE

 

Contents


Unit 1. Chemistry and matter
1.1. Basic concepts
1.2. Fundamental laws of chemical reactions. Atoms
1.3. Compounds and chemical formula
1.4. Composition of compounds
1.5. Mixtures, solutions and solubility

Unit 2. Chemical reactions and stoichiometry
2.1. Chemical reaction and chemical equation
2.2. Stoichiometry of chemical reactions
2.3. Gases
2.3. Aqueous reactions

Unit 3. Chemical equilibrium
3.1. Basic concepts
3.2. Equilibrium constant and chemical equation
3.3. Numerical importance of the equilibrium constant
3.4. The reaction quotient, Q
3.5. Le Chatêlier’s principle
3.6. Acid-base equilibria and the pH scale
Lab. session 1: Solutions and titration

Unit 4. Energy and Chemistry
4.1. Basic concepts
4.2. The First Law of Thermodynamics: heat, work and enthalpy
4.3. Spontaneous processes
4.4. Entropy.
4.6. The Second Law of Thermodynamics.

Unit 5. Chemical kinetics
5.1. Reaction rates
5.2. Concentration and reaction rate
5.3. Rate laws
5.4. The change of concentration with time.
5.5. Temperature and reaction rate
5.6. Reaction mechanisms
5.7. Catalysis
Lab. session 2: The aluminothermic reaction

Unit 6. Atomic models
6.1. From classical physics to quantum mechanics
6.2. Line spectra and the Bohr model
6.3. The wave behaviour of matter
6.4. Quantum mechanics and atomic orbitals
6.5. Many-electron atoms
6.6. Electronic configurations and the Periodic Table
6.7. Periodic properties

Unit 7. Chemical bond I
7.1. Chemical bonds, Lewis symbols and the octet rule
7.2. Ionic bonding
7.3. Covalent bonding
7.4. Strength of covalent bonds

Unit 8. Chemical bond II
8.1. The VSEPR model
8.2. Molecular polarity
8.3. Molecular-orbital model
8.4. Molecular-orbital model for metals

Unit 9. Intermolecular forces and liquids
9.1. Intermolecular forces
9.2. Solubility and the solution process
9.3. Phases, phase changes and phase diagrams
9.4. Liquids: boiling point, vapor pressure, surface tension, viscosity

Unit 10. Solids
10.1. Amorphous solids and the short-range order. Glass transition temperature
10.2. Crystalline solids, the long-range order and the unit cell
10.3. Bonding in solids

Unit 11. Materials
11.1. Materials science and classes of materials
11.2. Ceramics
11.3. Polymers
11.4. Alloys
11.5. Semiconductors

5.4. Course planning and calendar

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SECTION

Topic

Nº hours

0 y 1

Presentation.

Atom (Topic 1) and the Periodic System (Topic 2)

10

2 y 3

The Chemical Bond (Topics 3, 4 y5) and  Intermoleculars Bonds(Topic 6)

12

4

Aggregation Sates (Topics 7, 8 y 9)

6

5

Introduction to the study of solutions (Topic 10)

8

6

Introduction to the study of reactions (Topics 11 y 12)

8

7

Organic Chemistry (Topic 13)

4

 

Practical Course

6

 

Exams

6

TOTAL

 

60

 

The dates of the final exams will be those that are officially published at  http://www.eupla.es/secretaria/academica/examenes.html.

 

DEFENCE

 

Before the start of the semester the course additional information will be published in the Moodle platform, which can be consulted at http://moodle.unizar.es after authentication with the student’s username and password.

This information will include the course planning, materials, bibliography and other recommendations to follow the course.

Information about general course calendars and timetables can also be found at the website of the Centro Universitario de la Defensa: http://cud.unizar.es.

 

5.5. Bibliography and recommended resources

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References and resources

Basic material prepared by the lecturer:

GONZÁLEZ PAÚLES, J. y BURBANO GARCÍA, G. Apuntes de Química para el Grado en Ingeniería Civil. Ed. Eupla. 2011. ISBN 978 84 694 0618 2

GONZÁLEZ PAÚLES, J. Química General. Apuntes del curso práctico. Ed. Eupla.2010. ISBN  978-84-692-8044-7

Power Point in moodle platform (https//moodle.unizar.es/)

 

BIBLIOGRAPHY

  • Gonzalez Paúles, J . Burbano García, G.. Apuntes de Química para el grado de ingeniería civil/Javier Gonzalez Paúles y Gloría Burbano García.. - 1ª Edición Eupla:La Almunia de doña godina(Zaragoza), 2011
  • González Paúles, J.. Química General. Apuntes del curso práctico/ Javier González Paúles. - 1ª edición Eupla:La Almunia de doña godina(Zaragoza), 2010
  • Química : un proyecto de la American Chemical Society / [versión española por Roberto Martínez-Alvárez, Mª Josefa Rodríguez Yunta, Luis Sánchez Martín] Barcelona [etc.] : Reverté, D.L. 2005
  • Química / Ronald J. Gillespie ... [et al.] ; versión española por Aurelio Beltrán Barcelona [etc.] : Reverté, D.L. 1990
  • Negro, José Luis. Iniciación al lenguaje químico inorgánico / José Luis Negro. Madrid: Alhambra, 1979
  • Nyman, C.J.. Problemas de química general y análisis cualitativo / C.J. Nyman y G.B. King ; traducción de A. López-Lago . - [1a ed. española] Madrid : AC, D.L.1978
  • Peterson, W.R. Formulación y nomenclatura química inórganica/ W.R. Peterson. - 14 edición Barcelona: Edunsa, 1987
  • Sienko, Michell J.. Problemas de química / M.J. Sienko Barcelona [etc.] : Reverté, D.L.1987

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Basic

Química: la ciencia central / Theodore L. Brown ... [et al.]; con la colaboración de Patrick Woodward; traducción, Laura Fernández Enríquez; revisión técnica, María Aurora Lanto Arriola . 12ª ed. México: Pearson Educación, 2014
Brown, L. S. y Holme, T. A. Chemistry for Engineering Students. 2nd ed. México D.F.: Cengage Learning, 2011
Chang, Raymond. Fundamentos de química / Raymond Chang; adaptación Pedro Ibarra Escutia; revisión técnica Isaías de la Rosa Gómez México D. F.: McGraw-Hill/Interamericana, cop. 2011
Problemas y cuestiones de química / María Teresa Aramendía ... [et al.] . - 1ª ed. Zaragoza: Centro Universitario de la Defensa, 2015
Smith, William F. Fundamentos de la ciencia e ingeniería de materiales / William F.Smith, Javad Hashemi; revisión técnica Ramón Esquivel González, Arturo Barba pingarrón , [traductor, Gabriel Nagore Cázares] . - 5ª ed. México D. F.: McGraw-Hill Interamericana, cop. 2014

 

Complementary

Callister, William D., Jr. Introducción a la ciencia e ingeniería de los materiales / William D. Callister, Jr.; [versión española por Pere Molera Solà  y Marc J. Anglada Gomila] . - [1ª] ed. en español, reimp. Barcelona [etc.]: Reverté, 2012
Chang, Raymond. Química / Raymond Chang; revisión técnica, Rodolfo Álvarez Manzo, Silvia Ponce López, Rosa Zugazagoitia Herranz; [traducción, Erika Jasso Hernán D' Bourneville] . - 10ª ed. México [etc.]: McGraw-Hill, cop. 2010
Experimentación en Química General. J. Martínez Urreaga et al. Thomson, 2006
López Cancio, J. A. Problemas de química, cuestiones y ejercicios. J. A. López Cancio. Prentice Hall, 2000
Peterson, W. R. Introducción a la nomenclatura de las sustancias químicas / W. R. Peterson Barcelona [etc.]: Reverté, D. L. 2010
Petrucci, Ralph H. Química general / Ralph H. Petrucci, William S. Harwood, F. Geoffrey Herring; con la colaboración de Scott S. Perry; traducción, Concepción Pando Gª-Pumarino, Nerea Iza Cabo; revisión técnica, Juan A. Rodríguez Renuncio . - 8ª ed., reimp. Madrid: Prentice Hall, cop. 2009